Dynamics of a single atom transition and problem of quantum jumps
A mechanism of quantum jumps for an atom which is being in a process its proceeding from one stationary energy state to another one is rather vague up to now. Some principle questions are arising to perplex most of the researchers when they deal with a single atom problem. For example:
What is a real physical mechanism of a quantum jump?
Where is the atom just as it leaves one stationary state but have not got at the other one yet?
How does a photon chance to find itself into the atom?
Whether is the photon really indivisible?
This work do not claim answering these points finally but the author would like to show some discrepancies arising while in discussions of the single atom behavior one attempt to combine the photon indivisibility principle with the energy conservation law.
Generally speaking in order to get it these points for the single atom , one should obviously coordinate an adequate theory, reliable experiments and philosophy based on causality with common sense. It well known that the quantum theory can not possibly get along in explaining a deterministic behavior of the single atom during its quantum jumps. As a matter of fact , both the Schroedinger's and its alternative Hysenberg's mechanisms of a quantum jump let us get no satisfactory explanation because both of them are based on a probability conception. Such an approach is obviously to except a determinism absolutely while we consider a concrete single atom as a real object. Certainly, the quantum approach is a very nice tool if we study incoherent behavior a lots of atoms, namely the atomic systems prepared by accidental way. However many a time the results obtained in such experiments are erroneously ascribed to the concrete single atom behavior instead of to apply this to an effective average atom which is identically indiscernible one, as it is required by the quantum principle itself. This I believe is a principle reason to many misunderstandings.
Experiments with the single atom are rather hard and became accessible only recently. There is ,however, another more preferable way to get realistic information about a single atom behavior. I mean that we can study a behavior of a great number of atoms density of which is so small (dilute crystals, gases) that the atoms can practically no influence each other. Preparing such ensembles coherently and suppressing relaxation channels we can deduce conclusions about the single atom behavior from a coherent response of the noninteracting atoms in the ensemble.
A great deal of the experiments based on coherency of atomic oscillations are available at present (photon echo, transient light induced gratings, free induction decay and the other optical transients^{1}).Using such phenomena one can trace a dynamic behavior of the atom while it is proceeding from one stationary state to another. Usually to adequately describe the optical transients the semiclassical approach is applied more successfully than the quantum electrodynamics. It turned out to make no sense in using the photon conception at all in order to fit the transient experimental data with the theory and real physical sense. Moreover the photon indivisibility principle as a main point of quantum electrodynamics appears to come to contradiction with the energy conservation law. In order to prove this assertion holds true let us consider a dynamics of energy behavior for a single atom in the wellknown problem of a fieldatom interaction. Let the atom be in the lowest energy state and subjected by a resonant steplike optical field with frequency and electric field strength

(1) 
the unit field strength vector .
An isolated atom (in a dilute gas or a solid as an impurity) can be considered as a twolevel system capable of being excited through an interaction of the electric dipole moment with an external optical field [1].The properties of a two level system are completely specified by the wave function

(2) 
which is a linear superposition of the 1 and 2 stationary states (  spindown and spinup eigenstates).The probability amplitudes are continuous functions on time,  eigenvalues of energy of the two level atom (stationary states).
When the atom subjected by the field (1) an evolution of its
wave function is governed by the nonstationary Schroedinger's equation

(3) 
where , is the fieldfree Hamiltonian and  the interaction operator in electric dipole approximation due to the external field

(4) 
where is the dipole moment operator of the transition and 
the electric field strength (1).
Following the substitution of (1), (2) and (4) into Eq.(3) we arrive to the wellknown equations for the probability amplitudes [2]
(5) 
where the detuning from resonance is at the transition frequency equaled to, the resonant Rabi frequency is , p  a projection of the dipole moment matrix element on the unit field strength vector .
We derive these equations in a usual fashion of a rotating
frame approximation under our initial conditions and ,
i.e. we consider the atom to be initially in the spindown state until the applied field to be turned on.
The coefficients are completely specifying the properties of this atom at any moment on the time interval before the pump field (1) to be turned off at any instant . A time dependent behavior of these coefficients can be obtained from Eqs.5 as follows
(6) 
Here the general (dnonresonant) Rabi frequency is
These functions can be used to find the average value of energy of the single atom after taking the mathematical expectation
(7) 
followed by inserting the wave function (2) and Hamiltonian into it , making use of the stationary Schroedinger's equations

(8) 
and orthonomality of the eigenstates .
As a result we obtain a time behavior of energy

(9) 
where the interaction Hamiltonian is represented through nondiagonal matrix elements of the dipole moment operator and the applied field as follows

(10) 
where one usually accept and .
Taking into account that and substituting the Ex.(6) into (9), we can obtain time behavior of energy of the single atom during transition from the stationary state to a higher one

(11) 
where the parameter q(t) is a real time dependent periodic function

(12) 
As to the highfrequency oscillations of the energy (the second and third terms in q(t) ) , they are rather small to be neglected at all because usually . Really, in experiments, the Rabi frequency is not more than 10^{10}s^{1 }at the frequency of optical transition of about 10^{15}s^{1 }. Therefore behavior of energy for the single atom during the spectroscopic transition is practically specified by the first term of to the q(t). As an example in F ig.1 , we show this behavior for two different situations: at exact resonance (frequency of the pump field is equal to ) and at detuning from resonance (at ) .
Fig.1. The dynamics of energy for the single atom during spectroscopic twolevel transition between the stationary states E_{1} and E_{2} (two examples)
A_{o}  amplitude of steplike laser probe field, units ,
 average value of energy (increase in units at time in ):
1 exact resonance ( )
2 detuning from resonance () at
Three important conclusions can be deduced from the analysis of this Fig and the Exs.(11,12):
Thus, in the case of detuning from resonance , the energy portion which the atom takes away from the applied field at any instant of time is less of , i.e. the photon energy. Logical conclusions follow from this: in this process the atom is no obliged to absorb an energy in the form of photons and the field is no obliged to give the energy in the form of photons. Both of these conclusions make doubt to the main principle of the quantum electrodynamics, namely to indivisibility of a photon. Moreover, if one to guess that indivisibility of a photon holds true we can arrive to once more contradiction concerning to the energy conservation law.
Let us discuss that more in detail.
While the atom is proceeding from the spindown state to the upper level its energy evolves deterministically, see Ex.(11). If the external field to be turned off at any time t_{e} the atom has to relax to the spindown level, i.e. the atom should return the amount of energy that is less one photon energy.
This portion should be returned by means of electromagnetic radiation due to the induced dipole moment. Accordingly to quantum electrodynamics this field should consist of photons with energy each. Thus having got the amount of energy less one photon the atom has to return an amount more one photon at least. This obviously contradicts to the main principle of nature, namely to conservation energy law.
This same situation occurs at the exact resonance excitation (,).In this case the atom may reach to the upper level only at the concrete instants
, m=1,3,5... 
(13) 
Only for these moments we can guess the atom to has adsorbed one photon and the field has lost one photon as well. However to the other instants this conclusion does not hold true. For example, let us turn off the pumping field at the moment ,i.e. when the atom is in superposition state in which it has a concrete induced dipole moment oscillating with a frequency and energy less than .
Consequently, if to admit indivisibility of the photon a violation of energy conservation law could be available at exact resonant conditions as well.
Thus in order to the main principle of the nature does not is violated we must conclude that the coherent optical field is able to give his energy back in any amount by no means photons.
Such a conclusion could be reasonable at supposition that a monochromatic coherent wave is no consist of photons at all. In this case a great many misunderstandings can be removed by a natural way. As a matter of fact the monochromatic wave could be considered as a special phase state. Certainly, the optical field can be prepared by means of photons, as a water in a glass by drops. However both we can no assert the water in the glass consists of drops because there are no drops in the glass at all and we are not obliged to guess the monochromatic field consisting of photons. All depends on a preparation way of the field. For example, an incoherent field can be consistent of photons because they do not interfere each other. But the field prepared coherently, for instance by lasers, is in a new photonless phase state (waterlike state) because in an active medium the induced radiation is coordinating reactions all of the dipoles in the volume.